What is defined as the presence of unpaired electrons in a substance?

Prepare for the ACS Inorganic Chemistry Test. Study with flashcards and multiple choice questions, each question has hints and explanations. Get ready for your exam!

Paramagnetism is characterized by the presence of unpaired electrons in a substance. These unpaired electrons have magnetic moments that are not canceled out by other electrons, allowing the substance to be attracted to an external magnetic field. When exposed to a magnetic field, paramagnetic materials align in the direction of the field, which is a result of the unpaired spins of the electrons.

In contrast, diamagnetism is present in materials that do not have unpaired electrons. These substances are generally repelled by a magnetic field due to the paired electrons that generate an opposing magnetic field. Ferromagnetism arises in materials where unpaired electrons align parallel to each other, resulting in a strong magnetic effect even without an external field. Antiferromagnetism occurs when neighboring unpaired electrons align in opposite directions, effectively canceling each other's magnetic moments.

Thus, the defining feature of paramagnetism — the presence of unpaired electrons — explains why the answer is correct, as it directly relates to the magnetic behavior of substances in the presence of a magnetic field.

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