What is the corresponding letter and orbital for L=2?

Prepare for the ACS Inorganic Chemistry Test. Study with flashcards and multiple choice questions, each question has hints and explanations. Get ready for your exam!

In quantum mechanics, the orbital angular momentum quantum number ( L ) describes the shape of an electron's orbital and the types of orbitals associated with different values of ( L ). For ( L = 2 ), the corresponding type of orbital is the d-orbital.

The notation for d-orbitals includes various symmetries that correspond to the specific electronic arrangements in crystal field theory. Commonly, these are represented as ( T_{2g} ) and ( E_g ). The ( T_{2g} ) designation is often utilized in octahedral coordination complexes, indicating a set of orbitals that are lower in energy due to the crystal field splitting, while ( E_g ) represents a higher-energy set of orbitals in the same coordination.

Therefore, the correct response associates ( L = 2 ) with d-orbitals and gives the appropriate symmetry labels ( T_{2g} ) and ( E_g ) that identify how these orbitals interact within a given crystal field environment.

Understanding this classification is crucial for predicting the electronic structure and chemical behavior of transition metal complexes, which heavily rely on their d-orbitals.

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