Which of the following orbitals has a degeneracy of 1?

Prepare for the ACS Inorganic Chemistry Test. Study with flashcards and multiple choice questions, each question has hints and explanations. Get ready for your exam!

The orbital with a degeneracy of 1 is the z2 orbital. To understand why, we need to consider the concept of degeneracy in quantum mechanics, which refers to the number of different quantum states of a system that have the same energy level.

The d orbitals, such as dx2-y2 and dxy, are part of a set of five degenerate d orbitals that exist at the same energy level in a free atom. These orbitals have the same energy but differ in their orientation and shape. Similarly, the p orbitals, including px, are also degenerate in groups of three, meaning that px, py, and pz all have the same energy in a hydrogen-like atom.

On the other hand, the z2 orbital is distinct in shape and has a different energy level compared to the other d orbitals. In many contexts, particularly within transition metal complexes, the z2 orbital is considered to be non-degenerate and exists as a single energy level due to its specific characteristics, which makes its degeneracy equal to 1.

Thus, the z2 orbital uniquely stands out as having a degeneracy of 1, whereas the other orbitals listed have a greater degree of degeneracy by being part of

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